Alumina bubble bricks are manufactured from hollow spheres of fused alumina, graded and bonded into a brick and fired. Because the voids are sealed spheres of alumina rather than voids left in a clay matrix, the material reaches a combination that ordinary insulation cannot: a bulk density of 1.35 to 1.70 g/cm3 together with refractoriness under load of 1650 to 1700°C at 0.1 MPa. That is the point of the material — low density and high refractoriness in the same brick.
XZK Group produces alumina bubble bricks in grades XZK-AB90, AB93, AB95 and AB99 at our Xinmi plant in Henan. They are used where an insulation layer is itself exposed to high temperature, as backing above a silica or mullite crown, in the hotter parts of the regenerator, behind suspended walls, around the doghouse and in the forehearth.
What Is an Alumina Bubble Brick?
The aggregate is the defining feature. Alumina is melted and dispersed so that it solidifies into hollow, roughly spherical shells, and those spheres become the aggregate of the brick. Each sphere has a dense alumina wall and a sealed gas-filled interior. Alumina content of the finished brick runs from 90% in AB90 to 99% in AB99, and it is carried almost entirely by the sphere material itself rather than by a lower-grade bond, which is why these bricks keep their refractoriness where a fireclay insulator would soften.
Manufacture begins with the spheres, which are graded by size before batching. Sphere size distribution controls the packing of the body and therefore its density: a well-graded charge packs more efficiently and gives a denser, stronger brick, while a higher proportion of large spheres gives a lighter brick that insulates better. The graded spheres are combined with a high-purity alumina bond, formed, and fired so that the bond sinters to the sphere walls without filling the spaces between them.
The performance mechanism is the closed, spherical pore. In a porous brick with open channels, hot gas can move through the body and carry heat by convection as well as conduction. A closed sphere traps still gas inside an alumina shell, so the only heat path through the material is conduction along the sphere walls and across the contact points between them. At the same time, the alumina wall resists the temperature that would soften the aluminosilicate bond of a conventional insulating firebrick.
The trade-off is mechanical. Cold crushing strength is 8 MPa in AB90 and 20 MPa in AB99, far below a dense corundum brick, so an alumina bubble brick is still a backup material and is not specified as a hot face in direct melt contact. What it does is extend the working temperature of the insulation course, allowing a lighter and cooler outer stack behind it while it absorbs the temperature that a standard insulating firebrick could not.
Key Properties
- Alumina content from 90% (AB90) to 99% (AB99), carried by the fused hollow spheres themselves, so refractoriness is not diluted by a low-grade bond.
- Low bulk density of ≤ 1.35 to ≤ 1.70 g/cm3 — roughly half the weight of a dense corundum brick and a third of a dense zircon brick — which keeps structural load off the crown and shell.
- Refractoriness under load from ≥ 1650°C (AB90) to ≥ 1700°C (AB95 and AB99) at 0.1 MPa, the property that separates this material from every aluminosilicate insulating brick.
- Cold crushing strength from ≥ 8 MPa (AB90) to ≥ 20 MPa (AB99), adequate for a backing course and for handling, but not a substitute for a dense structural brick.
- Very low iron oxide, from ≤ 0.5% in AB90 to ≤ 0.1% in AB99, important where the insulation sits above a glass bath and any volatile species can migrate downward into the melt.
- Closed spherical porosity, which suppresses convection through the body and slows the penetration of alkali vapour that would attack an open-pored insulator.